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Title:
Organic chemistry demystified / Daniel R. Bloch.
Author:
Bloch, D. R.
Publication Information:
New York : McGraw-Hill, ©2012.
Call Number:
QD253.2 .B56 2012
Abstract:
Offers a complete overview of organic chemistry and includes detailed examples, quizzes, and a final exam.

Overview: You don't need genius DNA to master organic chemistry! Whether you're taking a chemistry class or studying for the MCAT or DAT, Organic Chemistry Demystified is your formulas for learning or reviewing fundamental concepts and theories step-by-step. This practical guide eases you into this sometimes challenging subject, starting with atomic structure and mass. As you progress, you will master organic chemistry essentials such as the reactivity of functional groups, the three-dimensional structure of molecules, reaction mechanisms, and more. You will understand how compounds are named and how to predict reactions. Detailed examples make it easy to understand the material, and end-of-chapter quizzes and a final exam help reinforce key ideas. It's a no-brainer! You'll learn about: Molecular orbitals and bonding. -- Acidic and basic properties of organic molecules. -- Structure and properties of functional groups. -- Characterization of molecules. -- Substitution and elimination reactions. -- Reaction mechanisms. -- Stereochemistry. -- Predicting reaction pathways. Simple enough for a beginner, but challenging enough for an advanced student, Organic Chemistry Demystified, Second Edition, helps you master this essential subject.
Edition:
2nd ed.
ISBN:
9780071767972
Series:
Demystified series

McGraw-Hill "Demystified" series.
Physical Description:
xv, 624 pages : illustrations ; 24 cm.
Contents:
Introduction -- Acknowledgments -- Structure And Bonding: -- Atomic structure -- Atomic number and atomic mass (weight) -- Electron energy levels -- Octet rule -- Valences -- Lewis structures -- Orbital shapes -- Quantum mechanics -- Bond formation -- Valence bond theory -- Molecular orbitals -- Bonding and antibonding MOs -- Bonding and 3-D molecular shape -- Curved arrows -- Electronegativity and bond polarity -- Dipole moments -- Formal charges -- Resonance structures -- Intermolecular forces -- Summary -- Quiz -- Acids And Bases: -- Arrhenius definition -- Bronsted-Lowry definition -- Conjugate acids and bases -- Equilibrium reactions -- Weak hydrocarbon acids -- Lewis definition -- summary-- Quiz -- Alkanes And Cycloalkanes: -- Sources of alkanes -- Acyclic and cyclic alkanes -- Nomenclature -- Formulas -- Structures -- Constitutional lsomers -- Cycloalkanes -- Naming compounds by the IUPAC system -- Physical properties -- Chemical properties -- Conformations of alkanes -- Conformations of cycloalkanes -- Summary -- Quiz -- Stereochemistry: -- Isomers -- Chiral compounds -- Stereocenters -- Chirality centers -- Enantiomers -- Racemic mixtures -- R/S system -- When the lowest priority group is not in the back -- Molecules with multiple asymmetric centers -- Enantiomers -- Diastereomers -- Meso compounds -- Fisher projections -- Rotating Fisher projections / structures -- Cyclic stereoisomers -- Naming cyclic stereoisomers -- Prochiral carbons (wanabees) -- Summary -- Quiz -- Structure And Properties Of Alkenes: -- Structure of alkenes -- Naming alkenes -- Common names -- Cis and trans isomers -- E/Z (easy) system -- Degrees of unsaturation -- Stability of alkenes -- Physical properties -- Chemical properties -- Curved arrow -- Summary -- Quiz -- Reaction Mechanisms: -- Thermodynamics -- Kinetics -- Carbocations -- Stereochemistry -- Hammond Postulate -- Regiochemical reactions -- Markovnikov rule -- Stereochemistry -- Rearrangement reactions of Carbocations -- Quiz -- Reactions Of Alkenes: -- Reaction with hydrogen halides inert solvents -- Reaction with hydrogen halides in protic solvents -- Oxymercuration-demercuration reactions -- Hydroboration-oxidation -- Halogenation in inert solvents -- Stereochemistry of Halogenation -- Halogenation in reactive solvents -- Radical bromination -- Formation of diols -- Double bond cleavage -- Hydrogenation -- Epoxides -- Cyclopropanes -- Summary -- Quiz -- Alkynes: -- Structure -- Nomenclature -- Physical properties -- Chemical properties -- Reactions with Bronsted-Lowry acids -- Reactions with HBr and peroxides -- Reactions with halogens -- Hydration reactions -- Hydroboration-oxidation reactions -- Hydrogenation/reduction reactions -- Oxidation reactions -- Acidity of alkynes -- Alkylation reactions -- Preparation of alkynes -- Summary -- Quiz -- Characterization: -- Chromatography -- Spectroscopy -- Infrared spectroscopy -- Ultraviolet spectroscopy -- NMR spectrometers -- ¹H NMR spectroscopy -- ¹³C NMR spectroscopy -- DEPT -- Mass spectrometry -- Summary -- Quiz -- Organohalides: -- Nomenclature -- Properties -- Preparation of halides -- Radical Halogenation -- Isomeric products -- Allylic halogenations -- Reactions of Organohalides -- Summary -- Quiz.

Nucleophilic Substitution And Elimination Reactions: -- Properties of nucleophiles -- Properties of bases -- Properties of substrate/electrophiles -- Properties of leaving groups -- Properties of solvents -- Second-order Nucleophilic substitution (Sn2) reactions -- First-order Nucleophilic substitution (Sn1) reactions -- Second-order elimination (E2) reactions -- First-order elimination (E1) reactions -- Summary of E1 and E2 reactions -- Summary -- Quiz -- Alcohols: -- Introduction -- Properties of alcohols -- Nomenclature -- Acidity and basicity of alcohols -- Reaction with active metals -- Preparation of alcohols -- Organometallic compounds -- Preparation of alcohols using Organometallic reagents -- Reactions of alcohols -- Conversion of alcohols to alkyl halides -- Dehydration reactions -- Summary -- Quiz -- Ethers: -- Nomenclature -- Properties -- Preparation of ethers -- Reactions of ethers -- Three-membered ether rings -- Summary -- Quiz -- Sulfur Compounds: -- Nomenclature -- Properties -- Reactions of sulfur compounds -- Summary -- Quiz -- Conjugated Systems: -- Stability of dienes -- Electrophilic addition to conjugated dienes -- Allylic cations, radicals, and anions -- Diels-alder reactions -- Summary -- Quiz -- Aromatic Compounds: -- Reactivity of aromatic compounds -- Nomenclature -- Kekulé structures -- Stability of benzene -- Resonance model -- Molecular orbital description of aromaticity -- Properties of aromatic, nonaromatic, and antiaromatic compounds -- Hückel's rule -- Heterocyclic compounds -- Aromatic ions -- Polycyclic aromatic compounds -- Summary -- Quiz -- Reactions Of Benzene And Other Aromatic Compounds: -- Electrophilic aromatic substitution -- Nucleophilic aromatic substitution -- More derivatives of benzene -- Multiple substitution reactions -- Electrophilic substitution in disubstituted benzenes -- Summary -- Quiz -- Aldehydes And Ketones: -- Introduction -- Nomenclature -- Physical properties -- Chemical properties -- Preparation of Aldehydes and ketones -- Hydration of alkynes -- Reduction of acid chlorides -- Reactions of Aldehydes and ketones with nucleophiles -- Wittig reactions -- Oxidation and reduction reactions -- Summary -- Quiz -- Carboxylic Acids: -- Nomenclature -- Three-dimensional structure -- Molecular orbital description -- Physical properties -- Acidity of carboxylic acids -- Preparation of carboxylic acids -- Derivatives of carboxylic acids -- Summary -- Quiz -- Derivatives Of Carboxylic Acids: -- Introduction -- Carboxylic acid halides -- Carboxylic acid anhydrides -- Carboxylic esters -- Amides -- Cyclic amides -- Imides -- Nitriles -- Summary -- Quiz -- Alpha-Substitution Reactions In Carbonyl Compounds: -- Enol and enolate anions -- Alpha-monohalogenation of aldehydes and ketones -- Alpha-beta unsaturated ketones -- Alpha-bromination of carboxylic acids -- Acidity of alpha-hydrogen atoms -- Malonic ester synthesis -- Acetoacetic ester synthesis -- Additional condensation reactions -- Summary -- Quiz -- Carbonyl Condensation Reactions: -- Aldol reactions -- Dehydration of aldol compounds -- Mixed or crossed aldol reactions -- Intramolecular aldol reactions -- Claisen condensation reactions -- Alpha-substitution reactions -- Summary -- Quiz -- Final exam -- Answer to quizzes and final exam -- Appendix A: Periodic table of the elements -- Appendix B: Families and functional groups -- Glossary -- Bibliography -- Index.
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